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The existence of the thermodynamic limit and the Van der Waals equation of state of a classical gas

โœ Scribed by A. Isihara


Publisher
Elsevier Science
Year
1974
Weight
405 KB
Volume
71
Category
Article
ISSN
0031-8914

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Improvement of the Van Der Waals equatio
โœ G. Soave ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 916 KB

The Van Der Waals equation of state has been modified in order to improve its accuracy. The introduction of a temperature dependence of the attraction term allows reproducing accurately purecompound vapour pressures. The modification of the mixing rules, with the infinite-pressure excess-freeenergy