The intIoducticjn of an average trajectory is much more powerful than can be appreciated from the derivations of the classical equations. This is discussed and exemplified by systems for which the general conditions derived will not be necessary conditions of applicability.
On the applicability of the classical trajectory equations in inelastic scattering theory
โ Scribed by Gert Due Billing
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 343 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Ey using the classical trajectory equations and an average trajectory we have been able to predict the single quantum transitions for the one-dimensional atom-diatom collision problem to within lo-30%. The double quantum transiiions POZ ye correct to within at least a factor of two.
๐ SIMILAR VOLUMES
An analytical method of calculating the energy transfer in classical, collinear atom-diatom collisions, based on the use of power-series expansions in the parameter w7 (o is the frequency of the molecular vibrations, 7 is an effective coihsion time) is presented. This method is applicable also for c