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On the kinetics of polymer degradation. X—Laser flash photolysis of poly-α-methylstyrene in chloroform solution

✍ Scribed by Seiichi Tagawa; Wolfram Schnabel


Book ID
116092491
Publisher
Elsevier Science
Year
1983
Weight
267 KB
Volume
3
Category
Article
ISSN
0144-2880

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On the kinetics of polymer degradation i
✍ S.W. Beavan; G. Beck; W. Schnabel 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 443 KB

Poly-ct-methylstyrene (PctMS) was degraded in CHCI 3 and CC14 solution by flash photolysis (2 = 265 nm). The degradation, as detected by light scattering measurements, is caused by the attack on PctMS by solvent radicals, assumed to be formed mainly by energy transfer processes. The direct effect di