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Picosecond pulse radiolysis and laser flash photolysis studies on polymer degradation of polystyrene and poly-α-methylstyrene

✍ Scribed by S. Tagawa; W. Schnabel; M. Washio; Y. Tabata


Publisher
Elsevier Science
Year
1981
Weight
384 KB
Volume
18
Category
Article
ISSN
0146-5724

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On the kinetics of polymer degradation i
✍ S.W. Beavan; G. Beck; W. Schnabel 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 443 KB

Poly-ct-methylstyrene (PctMS) was degraded in CHCI 3 and CC14 solution by flash photolysis (2 = 265 nm). The degradation, as detected by light scattering measurements, is caused by the attack on PctMS by solvent radicals, assumed to be formed mainly by energy transfer processes. The direct effect di