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On the Kinetics of Polymer Degradation in Solution. II. Laser Flash Photolysis Studies on Poly(phenyl vinyl ketone) and Butyrophenone

✍ Scribed by Beck, G.; Dobrowolski, G.; Kiwi, J.; Schnabel, W.


Book ID
126028397
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
353 KB
Volume
8
Category
Article
ISSN
0024-9297

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On the kinetics of polymer degradation i
✍ S.W. Beavan; G. Beck; W. Schnabel πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 443 KB

Poly-ct-methylstyrene (PctMS) was degraded in CHCI 3 and CC14 solution by flash photolysis (2 = 265 nm). The degradation, as detected by light scattering measurements, is caused by the attack on PctMS by solvent radicals, assumed to be formed mainly by energy transfer processes. The direct effect di