Tltc prcscnt study introduces ;I simplified method for :rcating vibrational-rot;ltionnl coupling during the collisionnl cschan~e of energy. This rorationnl couplinp modifies the vibrational cncrgy mismatch, wo and is a dominant cffcct, working to make the actu;ll energy mismatch smtilcr than the app
On the importance of multiquantum vv transitions in CO
β Scribed by Gert Due Billing; Mario Cacciatore
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 300 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The dependence of the probability of v -1 --, v vibrational excitations in molecule-molecule collisions on the vibrational quantum number v has been studied for v up to 7. This nominally VT energy transfer process can be strongly affected by the participation of VV mode particularly among high-lying
In a calculation of the dissociation constant of hydrogen in arpn, it is shown that multiplequantum transitions are importint near the dissociation limit. The transition probabilities between the vibrational states are obtained by Nth order semi-classical perturbation theory. Reasonable grcement wit