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The importance of higher order vibronic mechanisms in radiationless transitions

✍ Scribed by Benjamin Scharf


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
376 KB
Volume
7
Category
Article
ISSN
0301-0104

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Considering a mod4 system it is shown that higher order viironic and spin orbit viironic mechanisms may incsesse the theoreticaZIy derived non-radiative decay rates dramatically\_ it is suggested that the incIusion of higher order mechanisms in the theoretica computations of non-radiative decay rate

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Near resotlsnce vibronic interactions in the Born-Oppenheimer approximation -pertinent to radiationless transitions and inhomogeneous line broadening -are shown to be independent of the refevant eIectronic energy separation and to be practically equivalent to those deduced in the crude adiabatic sch