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On the impedance of galvanic cells: XIV. The impedance and admittance of streaming mercury electrodes; experimental verification

โœ Scribed by A. B. Ijzermans; J. H. Sluyters

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
491 KB
Volume
84
Category
Article
ISSN
0165-0513

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๐Ÿ“œ SIMILAR VOLUMES

On the impedance of galvanic cells: II.
On the impedance of galvanic cells: II. Experimental verification
โœ J. H. Sluyters; J. J. C. Oomen ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 391 KB

## Abstract It is shown by experiment that both types of frequency dependency of the cell impedance, treated in Part I, occur. From the results the diffusion constant of the Hg^++^~2~ ion in 1__M__ HClO~4~ and the reaction rate constant of the zinc amalgam electrode in 1__M__ NaClO~4~ + 10^โˆ’3^__M__

On the impedance of galvanic cells: V. T
On the impedance of galvanic cells: V. The impedance of a galvanic cell with two plane parallel electrodes at short distance
โœ J. H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

## Abstract It is shown both by calculation and experimentally that in a galvanic cell with two plane electrodes, through which an alternating current flows, the concentration waves interfere if the distance of the electrodes is of the order of a wave length.

On the impedance of galvanic cellsโ€”XVI:
On the impedance of galvanic cellsโ€”XVI: The impedance of the dropping mercury electrode in aqueous 1 M KCl with K+ discharge
โœ M. Sluyters-Rehbach; J.H. Sluyters ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 604 KB

The discharge of K+ ions at the dropping mercury electrode (dme) in 1 M KC1 solution at 25ยฐC has been studied by means of analysis of the electrode impedance at different frequencies, using the complex plane method. It is shown that the electrode reaction is almost entirely diffusioncontrolled, but