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On the impedance of galvanic cells: II. Experimental verification

✍ Scribed by J. H. Sluyters; J. J. C. Oomen

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 391 KB
Volume: 79
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19600791014

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✦ Synopsis

Abstract

It is shown by experiment that both types of frequency dependency of the cell impedance, treated in Part I, occur. From the results the diffusion constant of the Hg^++^~2~ ion in 1__M__ HClO~4~ and the reaction rate constant of the zinc amalgam electrode in 1__M__ NaClO~4~ + 10^−3^M HClO~4~ base electrolyte are calculated. In addition the value of the double layer capacity of the zinc amalgam electrode is reported.

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