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On the impedance of galvanic cells: I. Theory

✍ Scribed by J. H. Sluyters

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
278 KB
Volume
79
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Impedances of galvanic cells are treated as complex quantities and graphical methods for the determination of reaction rate constants of the redox reactions, double layer capacities, ohmic resistances and diffusion constants are proposed.

πŸ“œ SIMILAR VOLUMES

On the impedance of galvanic cells: II.
On the impedance of galvanic cells: II. Experimental verification
✍ J. H. Sluyters; J. J. C. Oomen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 391 KB

## Abstract It is shown by experiment that both types of frequency dependency of the cell impedance, treated in Part I, occur. From the results the diffusion constant of the Hg^++^~2~ ion in 1__M__ HClO~4~ and the reaction rate constant of the zinc amalgam electrode in 1__M__ NaClO~4~ + 10^βˆ’3^__M__

On the impedance of galvanic cells: V. T
On the impedance of galvanic cells: V. The impedance of a galvanic cell with two plane parallel electrodes at short distance
✍ J. H. Sluyters πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 276 KB

## Abstract It is shown both by calculation and experimentally that in a galvanic cell with two plane electrodes, through which an alternating current flows, the concentration waves interfere if the distance of the electrodes is of the order of a wave length.

On the impedance of galvanic cells: III.
On the impedance of galvanic cells: III. Applications to alternating current polarography
✍ Miss M. Rehbach; J. H. Sluyters πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 500 KB

## Abstract The theory described in part I of this series __J. H. Sluyters__, Rec. trav. chim. **79**, 1092 (1960). is applied to alternating current polarography by treating the complex cell impedance and cell admittance as functions of d.c. voltage. It is proposed to plot a.c. polarograms in th