On the Gallanyls R*3Ga2· and R*4Ga3· As Well As Gallanides R*3Ga2− and R*4Ga3− (R* = SitBu3) − Syntheses, Characterization, Structures
✍ Scribed by Nils Wiberg; Thomas Blank; Kerstin Amelunxen; Heinrich Nöth; Jörg Knizek; Tassilo Habereder; Wolfgang Kaim; Matthias Wanner
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 432 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
The synthesis, properties and X-ray single crystal structure bridges. In contrast, compounds 2 and 3a-b (R = CH 3 , C 2 H 5 ) are monomeric in the solid state. The suitability of the analysis of the intramolecularly adduct-stabilised organogallium bisazide (N 3 ) 2 Ga[(CH 2 ) 3 NMe 2 ] (1), the mono
In, Tl) and NaR\* via isolable R\* 2 ECl (reaction of GaCl 3 and NaR\* leads to R\* 2 GaէGaR\* instead of R\* 2 Ga-GaR\* 2 ), (ii) from EBr (E = In, Tl) and NaR\* or NaRЈ (reaction of AlBr or GaBr and NaR\* leads to R\* 4 Al 4 or R\* 8 Ga 18 and R\* 8 Ga 22 ), (iii) from NaGa 2 R\* 3 and Me 3 SiCl.