An upper limit to the relavation time of the first c.rcltcd electronic \mgIut st,ite (St) of a?ulcnc m cyclohcxanc ha\ been dctcrmincd for two cxcltatlon frequcncics. The lifctlmes of St cxcitcd by tingle picosecond duration optlcal pulses OI irequency 18910 crri' and 16OOC cm"' arc 5 1 ps and 5 2 p
On the electronic relaxation processes of carbonyl compounds of azulene in solution
β Scribed by G. Eber; S. Schneider; F. Doerr
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 555 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0047-2670
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A mode-locked dye laser is used to generate the S+J TPF pattern of azulene and some of its derivatives. Since none of the patterns shows a Iarger width at half maximum than the one obtained with dimethyl-POPOP, a lifetime of less than 1 ps has to be postulated for 'the excited vlbronic levels Sr,, o
Relaxation processes of the singlet excited states of carotenoids containing a carbonyl group were investigated in relation to the molecular structure around the carbonyl group. The relative quantum yield of fluorescence from the allowed Sz state to the forbidden S, state follows the energy gap law