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On the dissolution-precipitation model of anodic film formation

โœ Scribed by A.K.N. Reddy


Publisher
Elsevier Science
Year
1970
Weight
250 KB
Volume
28
Category
Article
ISSN
0022-0728

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โœฆ Synopsis


A renewed discussion 1'2 on the validity of the dissolution-precipitation (D-P) model for anodic film formation needs to be prefaced with the following comments :

A. The experimental facts relevant to the anodic formation, for example of calomel films, have been obtained under galvanostatic 3'4 and potentiostatic 5 conditions. A detailed analysis of the discharge-nucleation (D N) model has not been carried out for galvanostatic conditions, perhaps because such an analysis is fraught


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