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On the conformation of β-bromo radicals

✍ Scribed by Deanna Nelson; M.C.R. Symons

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
122 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis

During the past few years we have assigned e.s.r. spectra to a-and B-brano-radicals (I and II),lS2 but recently both our assignments have been dismissed in favour of others. 3S4 In the previous letter5 a case has been presented in favour of our a-bromo and B-bromo assigrrments: here we wish to defend our &bromo assignment and to propose an alternative structure for the species detected by Lloyd et al. and assigned structure III.4

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📜 SIMILAR VOLUMES

On the conformation of β-haloalkyl radic
On the conformation of β-haloalkyl radicals
✍ David E. Wood; Roger V. Lloyd 📂 Article 📅 1976 🏛 Elsevier Science 🌐 French ⚖ 229 KB

We have previously reported that the a-bromo-tert-butyl radical (I) is produced by the x-ir-1 radiation of isobutyl bromide in an adamantane matrix. In view of a recent claim by Nelson and 2 Symons that the salne spectrum could also be obtained by the irradiation of tert-butyl bromide in adamantane