Conformation of perfluoroalkyl radicals in the solid phase
β Scribed by S. R. Allayarov; A. I. Mikhailov; V. P. Mel'nikov; I. M. Barkalov
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 345 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
We have previously reported that the a-bromo-tert-butyl radical (I) is produced by the x-ir-1 radiation of isobutyl bromide in an adamantane matrix. In view of a recent claim by Nelson and 2 Symons that the salne spectrum could also be obtained by the irradiation of tert-butyl bromide in adamantane
During the past few years we have assigned e.s.r. spectra to a-and B-brano-radicals (I and II),lS2 but recently both our assignments have been dismissed in favour of others. 3S4 In the previous letter5 a case has been presented in favour of our a-bromo and B-bromo assigrrments: here we wish to defen