Differences between vibrational and rotational rehsation patterns disappex and similarities are reveaIed by\_trxtsforming from stite to er.ergy distributions\_ This IblIows from the constant state density of both osciilators and rotors and the exponential gap 1zw governing their relaxation A simple.
On rotational relaxation of spherical gas molecules
โ Scribed by A.S. Cukrowski
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 341 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Methods for calculating the rotational constants of floppy triatomic molecules and atom-linear molecule complexes are discussed. It is shown that previously published equations relating the rotational constants to expectation values of moments of inertia correspond to an approximate separation of ro
## Vlbrational-rotatlonal couphng, due to the fact that the center of interaction IS displaced from the center of mass in a heteronuclear diitomrc molecule, provides a mechanism for nonradiatwe vibrational relazxation of diitomic impurities in matrlces. A theoretical expresaon for the rate constan