✦ LIBER ✦

Role of rotational-translational coupling in vibrational relaxation of matrix-isolated diatomic molecules

✍ Scribed by D.J. Diestler; H.Douglas Ladouceur

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 610 KB
Volume: 70
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85336-x

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✦ Synopsis

Vlbrational-rotatlonal

couphng, due to the fact that the center of interaction IS displaced from the center of mass in a heteronuclear diitomrc molecule, provides a mechanism for nonradiatwe vibrational relazxation of diitomic impurities in matrlces. A theoretical expresaon for the rate constant in semiquantitative agreement with experiment is derived..

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