Differences between vibrational and rotational rehsation patterns disappex and similarities are reveaIed by\_trxtsforming from stite to er.ergy distributions\_ This IblIows from the constant state density of both osciilators and rotors and the exponential gap 1zw governing their relaxation A simple.
Rotational relaxation numbers for the isotopic molecules of N2 and Co
✍ Scribed by P.G. Kistemaker; A. Tom; A.E. De Vries
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 688 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0031-8914
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📜 SIMILAR VOLUMES
Calculations of cross sections and rate constants are reported for the vibrationti relaution of CO in collision sith 3He and 4He. Results computed using a semiclassical technique and a vibrational close-coupling. rotational infmitearder sudden method are compared.
## Abstract An approximate analytical solution of relaxation in a low‐pressure system with exponential transition probabilities is given for vibrational–rotational energy transfer in the dissociation of diatomics. The main assumption is that the rotational degrees of freedom are in thermal equilibr
The moderately exotherrnic ion-molecule reaction O+ t Hz and its isotopic variants have been the subject of several dynamical studies in our group. In this work we report an extensive quasiclassical trajectory study on the dynamics of this system at different initial relative energies considering a