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On-line recording of13C/12C ratios and mass spectra in one gas chromatographic analysis

✍ Scribed by Meier-Augenstein, Wolfram

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
417 KB
Volume
18
Category
Article
ISSN
0935-6304

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✦ Synopsis

An isotope ratio mass spectrometer and an ion trap mass spectrometer have been coupled in parallel to one gas chromatograph. Using this arrangement both the 13C/12C ratio and the mass spectrum of a given compound can be measured simultaneously under identical gas chromatographic conditions. Although column connection fittings are employed to split the capillary eluate, chromatographic performance was barely impaired. Development of the system has been monitored by recording 6I3C values of the constituents of Grob test mixture no. 2. The accuracy and reliability of system performance has also been tested.

5

-28.27 0.12 5 a'The GC analyses were performed using the OV-1701-OH column.

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