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Olefinic cyclizations promoted by Beckmann rearrangement of oxime sulfonate

✍ Scribed by Sakane, Soichi; Matsumura, Yasushi; Yamamura, Yoshihiro; Ishida, Yasuko; Maruoka, Keiji; Yamamoto, Hisashi

Book ID
124097381
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
395 KB
Volume
105
Category
Article
ISSN
0002-7863

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Olefinic cyclization promoted by beckman
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The acid-catalyzed cyclization of olefinic oxime mesylates has been successfully applied for the synthesis of g-muscone and related macrocycles. We have recently shown that a double bond may become involved in the Lewis acid-catalyzed rearrangement of a suitably constituted olefinic oxime sulfonate

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