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Additions and Corrections - Organoaluminum-Promoted Beckmann Rearrangement of Oxime Sulfonates

โœ Scribed by Maruoka, Keiji; Miyazaki, Tohru; Ando, Mamoru; Matsumura, Yasushi; Sakane, Soichi; Hattori, Kazunobu; Yamamoto, Hisashi


Book ID
127288548
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
108 KB
Volume
105
Category
Article
ISSN
0002-7863

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Olefinic cyclization promoted by beckman
โœ Soichi Sakane; Keiji Maruoka; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

The acid-catalyzed cyclization of olefinic oxime mesylates has been successfully applied for the synthesis of g-muscone and related macrocycles. We have recently shown that a double bond may become involved in the Lewis acid-catalyzed rearrangement of a suitably constituted olefinic oxime sulfonate