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Olefin Metathesis: Catalyst Development, Microwave Catalysis, and Domino Applications

✍ Scribed by Aitken, Steven G.; Abell, Andrew D.


Book ID
118033179
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2005
Tongue
English
Weight
287 KB
Volume
58
Category
Article
ISSN
0004-9425

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An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a