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Synthesis and Application of a Permanently Immobilized Olefin-Metathesis Catalyst

✍ Scribed by Stephan C. Schürer; Simon Gessler; Nicole Buschmann; Siegfried Blechert

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
119 KB
Volume
39
Category
Article
ISSN
0044-8249

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An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a