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ChemInform Abstract: From Olefin Cyclopropanation to Olefin Metathesis Through Catalyst Engineering: Recent Applications of Olefin Metathesis to Fine Organic Synthesis and to Polymer Chemistry

✍ Scribed by A. F. Noels; A. Demonceau


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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From olefin cyclopropanation to olefin m
✍ A. F. Noels; A. Demonceau πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 173 KB πŸ‘ 1 views

An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a