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Octahedral metal carbonyls. XXV. Kinetics and mechanism of reactions of (ethylenedisphosphine)tetracarbonylmolybdenum(0) with lewis bases

✍ Scribed by G.R. Dobson; A.J. Rettenmaier

Book ID
117122811
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
616 KB
Volume
6
Category
Article
ISSN
0020-1693

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo