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Octahedral metal carbonyls. : XIX.Kinetics of the reactions of triphenylgermyl- and triphenylstannylpentacarbonylmanganese(0) with phosphines

✍ Scribed by G.R. Dobson; E.P. Ross

Book ID
114041737
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
484 KB
Volume
5
Category
Article
ISSN
0020-1693

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo