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Octahedral Metal Carbonyls. XXXV. Mechanism of the Reaction of 2,2'-Dipyridyltetracarbonylchromium(0) with Alkyl Phosphites

✍ Scribed by McKerley, Billy J.; Faber, Gary C.; Dobson, Gerard R.


Book ID
126451418
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
85 KB
Volume
14
Category
Article
ISSN
0020-1669

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Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo