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Octahedral metal carbonyls. XVI. Kinetic investigation of the second step of the reaction of o-phenanthrolinetetracarbonylmolybdenum with Lewis bases

✍ Scribed by Shrader, Douglas; Ross, Earl P.; Jernigan, Robert T.; Dobson, Gerard R.


Book ID
126799133
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
515 KB
Volume
9
Category
Article
ISSN
0020-1669

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Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo