Observations on the synthesis and characterization of N,N′,N″-tris-(dimethylaminopropyl)hexahydro-s-triazine and isolable intermediates
✍ Scribed by W. J. Kauffman
- Book ID
- 112123432
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1975
- Tongue
- English
- Weight
- 209 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Treatment of glutathione (GSH) with formic acid and acetic anhydride leads to preparation of crystalline \(N\) formyl GSH. This is the first characterized preparation of \(N\)-formyl GSH; this product was previously erroneously thought to be \(N\)-acetyl GSH. Authentic \(N\)-acetyl GSH (crystalline)
The lowest singlet state of &riazine is characterized as 'E" arising fro? k' -+ err promotion (II+ IC\*). The state has angular morn&turn corresponding tog = 0.24. The state is also subject to a fkst+nier Stark effect (a = 0.53D) due to electric field induced interactions of 2s and 2p eIectrons. we
## Abstract The 5‐substituted tetrazole ring was reacted in the gas phase with an acyl ion generated as the secondary reactive chemical ionization plasma in the mass spectrometer. The product ions obtained, among others, were proposed as the rearranged 2,5‐disubstituted‐1,3,4‐oxadiazole nucleus. It