Observations on the permanganate oxidation of unsaturated esters
โ Scribed by L. R. Eshelman; Earl G. Hammond
- Book ID
- 112806821
- Publisher
- Springer-Verlag
- Year
- 1958
- Tongue
- English
- Weight
- 559 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0003-021X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract A study was made on permanganate oxidation of olefinic and acetylenic alcohols in aqueous alkali media. Deprotonation constants of alcohols can be calculated from the kinetic data. The rate constant of alkoxide group oxidation exceeded that of the unsaturated bond. For oxidation of the
Swmnary: Potassium permanganate adsorbed on solid supports can be used to oxidize unsaturated secondary alcohols to the corresponding ketones without degradation of the carbon-carbon double bonds. The adsorption of reagents onto solid supports is known to induce changes in the reactivity and selecti