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Observation of the quasibound energy levels and tunnelling lifetimes in the Na2 B1Πu state

✍ Scribed by H.J. Vedder; G.K. Chawla; R.W. Field

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
576 KB
Volume
111
Category
Article
ISSN
0009-2614

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✦ Synopsis

All quasibound vibrational encr~y levels U' = 27-33 of the NaZ B 'no state arc accessed via a triple resonance C\CitatiOn scheme: cw modulated gain spectroscopy (MCS). Two independent analyses involve a Pad&type near-dissociation representation of the observed energies and non-linear least-squares fits to the lineshapes. The results arc values for the barrier hei$it (379.3 f 2.3 cm-* above the center of gravity of the 3s + 3p separated atom limit), the total number of quasibound. rotationless energy lcvcls (~'~a, = 33). and tunnellin~ lifetimes for u' = 33.3.

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