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Lifetimes of F2+ and Cl2+ in the A2Πu state

✍ Scribed by E. Castellucci; G. Dujardin; S. Leach; R.P. Tuckett

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 686 KB
Volume: 116
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80139-1

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✦ Synopsis

The PIFCO techruque. rn which mass-selected photolon-fluorescence photon coinadeaces are counted. IS used to deterrmne the lifetime of the A*rI, state of FZ+ and Cl : Values of 1.4 ps (F,+ ) and 054 ps (Cl: ) are measured, and they are compared with hfetlme measurements by other methods The Fc rcsuh IS used to dete-e the electronic transItion moment F of the A*II,-X *IIs transitIon to be 0 51 au. in excellent agreement wrih ab lnitlo cakulauons OsaUator swengtbs of t.hc A-X ' Permanent address: Dlpartunento & Chimxa, Umversitg do Flrenze, Floienq Italy.

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