𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Observation of a P/M interconversion of a gold–phosphine helicate via   31P NMR

✍ Scribed by Schuh, Walter; Kopacka, Holger; Wurst, Klaus; Peringer, Paul


Book ID
125981554
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
88 KB
Volume
21
Category
Article
ISSN
1359-7345

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Interconversion of diastereomeric comple
✍ Hansruedi Bircher; Bruce R. Bender; Wolfgang von Philipsborn 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 499 KB

## Abstract Rhodium(I) complexes containing chiral chelating diphosphines, e.g. __R__,__R__‐dipamp [(__R__,__R__)‐1,2‐bis(__o__‐methoxy‐phenylphenylphosphino)ethane] or __S__,__S__‐chiraphos [(2__S__,3__S__)‐bis(diphenylphosphino)butane] and a prochiral olefin, e.g. methyl (__Z__)‐α‐acetamidocinnam

Distance between phosphine-sulfide sidec
✍ Christopher A Klug; Daniel R Studelska; Guohua Chen; Scott R Gilbertson; Jacob S 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 356 KB

Dipolar restoration at the magic angle (DRAMA) has been used to measure the 31P-31P internuclear distance between phosphine-sulfide substituted sidechanins on the fourth and eighth residues of a 12-residue helical peptide. The 7.4 A distance is the same for the peptide lyophilized in bulk or isolate