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A 31 P NMR STUDY OF TERTIARY PHOSPHINE COMPLEXES OF PLATINUM(II) AND PALLADIUM(II)

โœ Scribed by Sabounchei, S. J.; Jodaien, V.; Samiee, S.


Book ID
120219702
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
183 KB
Volume
179
Category
Article
ISSN
1042-6507

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15N-NMR. and 31P-NMR. Studies of palladi
โœ Herbert Motschi; Paul S. Pregosin; Luigi M. Venanzi ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 561 KB

NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between