𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Observation of 91Zr NMR in zirconium-based metals and oxides

✍ Scribed by T.J. Bastow; M.E. Smith; S.N. Stuart

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
481 KB
Volume
191
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The characterisation by "Zr NMR at room temperature is reported for Zr metal (hexagonal close-packed), ZrH2 (tetragonal), ZrC (cubic), ZrCo (cubic), ZQ (monoclinic), ZrQ (3 mol% Y203, tetragonal) and ZrOz (9.3 mol% MgO). The density of states deduced from the Knight shift for zirconium metal agrees with band structure calculations. It is shown for the first time that the quadrupolar lineshape distinguishes between the various zirconia-based phases.

πŸ“œ SIMILAR VOLUMES

Transition Metal (53Cr, 59Co, 91Zr, and
Transition Metal (53Cr, 59Co, 91Zr, and 95Mo) and 14N NMR Spectroscopy of Coordination Compounds Containing Nitrogen Donor Ligands in Low-Viscosity Fluids
✍ Sander Gaemers; Jeroen Groenevelt; CornelisΒ J. Elsevier πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 297 KB

Appreciable decreases of the line widths of NMR resonances of the quadrupolar nuclei 14 N, 53 Cr, 59 Co, 91 Zr, and 95 Mo have been obtained in supercritical solvents and in low-viscosity liquefied gases. Several Ξ±-diimines R 1 N=C(R 2 )-C(R 2 )= NR 1 and their coordination compounds have been studi

Low-Temperature Deposition of Zirconium
Low-Temperature Deposition of Zirconium Oxide–Based Nanocrystalline Films by Alternate Supply of Zr[OC(CH3)3]4 and H2O
✍ K. Kukli; M. Ritala; M. LeskelΓ€ πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 429 KB πŸ‘ 1 views

Zirconium oxide thin films were grown by atomic layer deposition (ALD) at low temperatures, ranging from 150 C to 300 C, by alternate surface reactions between Zr[OC(CH 3 ) 3 ] 4 and H 2 O. The films grown in the temperature range 200Β± 300 C were nanocrystalline. No films could be deposited above 30