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Observation and Characterization of the CH 3 S(O)CH − and CH 3 S(O)CH − ·H 2 O Carbene Anions by Photoelectron Imaging and Photofragment Spectroscopy

✍ Scribed by Velarde, Luis; Habteyes, Terefe; Glass, Richard S.; Sanov, Andrei


Book ID
126320614
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
962 KB
Volume
113
Category
Article
ISSN
1089-5639

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UV absorption spectra of HO2, CH3O2, C2H
✍ Ole J. Nielsen; Matthew S. Johnson; Timothy J. Wallington; Lene K. Christensen; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0