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Obituary: Jacques H. van Boom (1937–2004)

✍ Scribed by van der Marel, Gijs; Ploegh, Hidde

Book ID: 118675218
Publisher: Nature Publishing Group
Year: 2004
Tongue: English
Weight: 141 KB
Volume: 431
Category: Article
ISSN: 0028-0836
DOI: 10.1038/431755a

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A convenient approach towards 2′-analogs

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The protected 3-C-methyl-a-D-allofuranose derivative 6, readily accessible from D-glucose, could be transformed into a diene scaffold which underwent ring-closing metathesis (RCM) to give the functionalized oxepines 10a,b. Further elaboration of 10a,b provided the 2%-zoapatanol analogs 3-5.