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o-DPPB-Directed Copper-Mediated and -Catalyzed Allylic Substitution with Grignard Reagents.

✍ Scribed by Peter Demel; Manfred Keller; Bernhard Breit

Publisher
John Wiley and Sons
Year
2006
Weight
50 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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o-DPPB-Directed Copper-Mediated and -Cat
o-DPPB-Directed Copper-Mediated and -Catalyzed Allylic Substitution with Grignard Reagents
✍ Peter Demel; Manfred Keller; Bernhard Breit 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 400 KB 👁 1 views

## Abstract The __ortho__‐diphenylphosphanylbenzoyl (__o__‐DPPB) group was explored as a directing leaving group in copper‐mediated and copper‐catalyzed allylic substitution with Grignard reagents. Complete control of chemo‐, regio‐ and stereoselectivity with complete __syn__‐1,3‐chirality transfer