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Enantioselective Copper-Mediated Allylic Substitution with Grignard Reagents Employing a Chiral Reagent-Directing Leaving Group.

✍ Scribed by Bernhard Breit; Daniel Breuninger

Publisher
John Wiley and Sons
Year
2005
Weight
41 KB
Volume
36
Category
Article
ISSN
0931-7597

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o-DPPB-Directed Copper-Mediated and -Cat
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## Abstract The __ortho__‐diphenylphosphanylbenzoyl (__o__‐DPPB) group was explored as a directing leaving group in copper‐mediated and copper‐catalyzed allylic substitution with Grignard reagents. Complete control of chemo‐, regio‐ and stereoselectivity with complete __syn__‐1,3‐chirality transfer

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.