O-Alkylation of Alkoxycarbonylalkylidenetriphenylphosphoranes
โ Scribed by Prof. Dr. H. J. Bestmann; Dipl.-Chem. R. Saalfrank; Prof. Dr. J. P. Snyder
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 218 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0044-8249
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๐ SIMILAR VOLUMES
## Polyphenylalkane derivatives Q 0720 Asymmetric Alkylation of N-Pivaloyl-o-benzylaniline. -Using sBuLi and (-)-sparteine, excellent yields and up to 76% e.e. in favor of the (S)-enantiomer are obtained by alkylation of compound (I) with alkyl halides or a tosylate. The use of (+)-sparteine surro
## Abstract A series of 27 OโalkylโOโarylโphenylphosphonothioates was prepared and studied by I. R.โ and N. M. R.โspectroscopy. The I. R.โspectra gave typical vibrations: PโOโalkyl, PโC~arom~ and PโOโC~arom~. Shifts in stretching frequencies were related with electronic properties of the substituen