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Nucleophilic displacements on halogen atoms. 9. Reactions of triarylphosphines with halopyridylmethyl phenyl sulfones

โœ Scribed by Jarvis, Bruce B.; Marien, Bruce A.

Book ID
127285584
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
606 KB
Volume
42
Category
Article
ISSN
0022-3263

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Nucleophilic displacements on halogen at
Nucleophilic displacements on halogen atoms. I. Reactivity of ฮฑ-halobenzyl phenyl sulfones toward triphenylphosphine
โœ Bruce B. Jarvis; John C. Saukaitis ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

In general the ease of reduction of alkyl halides increases as the series progresses, RCl<RBr <RI. Although the literature in this area contains many references to reductions which occur via displacement by nucleophiles on the halogen atom in alkyl halides', there have been few kinetic studies made.