Nucleophilic displacements on halogen atoms. I. Reactivity of α-halobenzyl phenyl sulfones toward triphenylphosphine

✍ Scribed by Bruce B. Jarvis; John C. Saukaitis

• Book ID: 104213907
• Publisher: Elsevier Science
• Year: 1973
• Tongue: French
• Weight: 225 KB
• Volume: 14
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)72440-3

✦ Synopsis

In general the ease of reduction of alkyl halides increases as the series progresses, RCl<RBr <RI. Although the literature in this area contains many references to reductions which occur via displacement by nucleophiles on the halogen atom in alkyl halides', there have been few kinetic studies made.

Recently, a study of the reaction of l-halo-1-alkynes with thiolate ions as