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The effect of the bond strength on the reactivity integral of displacement reactions of hot halogen atoms: The reaction of hot chlorine atoms with methyl iodide

โœ Scribed by Zeev B. Alfassi; Saadia Amiel

Book ID
115974214
Publisher
Elsevier Science
Year
1976
Weight
204 KB
Volume
38
Category
Article
ISSN
0022-1902

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โœ C.C. Chou; D.D. Wilkey; F.S. Rowland ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 194 KB

The reactions with CHjF of photochemically produced tritium atoms from TBr have been studied at various v+xvelengths. The energy threshold is lower and the relative yield higher for F replacement than for H repkement in CHaF. These near-threshold substitution reactions are consistent with an inversi