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Nucleophilic Catalysis of the Iodine—Zinc Exchange Reaction: Preparation of Highly Functionalized Diaryl Zinc Compounds.

✍ Scribed by Florian F. Kneisel; Maximilian Dochnahl; Paul Knochel

Publisher
John Wiley and Sons
Year
2004
Weight
199 KB
Volume
35
Category
Article
ISSN
0931-7597

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Nucleophilic Catalysis of the Iodine–Zin
Nucleophilic Catalysis of the Iodine–Zinc Exchange Reaction: Preparation of Highly Functionalized Diaryl Zinc Compounds
✍ Florian F. Kneisel; Maximilian Dochnahl; Paul Knochel 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 148 KB

Halogen-metal exchange reactions are among the most powerful methods for preparing organometallic reagents. Pioneered by Wittig et al. [1] and Gilman et al., [2] the halogen-lithium exchange has become an important method for the preparation of functionalized aryl and heteroaryl lithium compounds. [