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Nucleophilic benzoylation using lithiated methyl mandelate as a synthetic equivalent of the benzoyl carbanion. Oxidative decarboxylation of α-hydroxyacids

✍ Scribed by Gonzalo Blay; Isabel Fernández; Pilar Formentin; Belén Monje; José R Pedro; Rafael Ruiz


Book ID
108371073
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
143 KB
Volume
57
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Catalytic Aerobic O
✍ G. BLAY; I. FERNANDEZ; P. FORMENTIN; J. R. PEDRO; A. L. ROSELLO; R. RUIZ; Y. JOU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Catalytic Aerobic Oxidative Decarboxylation of α-Hydroxy Acids. Methyl Mandelate as a Benzoyl Anion Equivalent. -The title reaction leading to ketones such as (II) is developed using a cheap and environmentally acceptable oxidant. The compounds (Ib)-(Ie) are prepared via alkylation of methyl mandel