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ChemInform Abstract: Catalytic Aerobic Oxidative Decarboxylation of α-Hydroxy Acids. Methyl Mandelate as a Benzoyl Anion Equivalent.

✍ Scribed by G. BLAY; I. FERNANDEZ; P. FORMENTIN; J. R. PEDRO; A. L. ROSELLO; R. RUIZ; Y. JOURNAUX

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Catalytic Aerobic Oxidative Decarboxylation of α-Hydroxy Acids. Methyl Mandelate as a Benzoyl Anion Equivalent.

-The title reaction leading to ketones such as (II) is developed using a cheap and environmentally acceptable oxidant. The compounds (Ib)-(Ie) are prepared via alkylation of methyl mandelate, therefore methyl mandelate can be considered as benzoyl anion equivalent (umpolung). -(BLAY, G.; FERNANDEZ, I.;

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