ChemInform Abstract: Nucleophilic Benzoylation Using Lithiated Methyl Mandelate as a Synthetic Equivalent of the Benzoyl Carbanion. Oxidative Decarboxylation of α-Hydroxyacids.

ChemInform Abstract: Catalytic Aerobic O

ChemInform Abstract: Catalytic Aerobic Oxidative Decarboxylation of α-Hydroxy Acids. Methyl Mandelate as a Benzoyl Anion Equivalent.

✍ G. BLAY; I. FERNANDEZ; P. FORMENTIN; J. R. PEDRO; A. L. ROSELLO; R. RUIZ; Y. JOU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Catalytic Aerobic Oxidative Decarboxylation of α-Hydroxy Acids. Methyl Mandelate as a Benzoyl Anion Equivalent. -The title reaction leading to ketones such as (II) is developed using a cheap and environmentally acceptable oxidant. The compounds (Ib)-(Ie) are prepared via alkylation of methyl mandel