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Nucleophilic addition to olefins. 18. Kinetics of the addition of primary amines and .alpha.-effect nucleophiles to benzylidene Meldrum's acid

✍ Scribed by Bernasconi, Claude F.; Murray, Christopher J.

Book ID: 121212980
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 839 KB
Volume: 108
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00277a032

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## 4, ' ) ' ) For solvent isotope effects in acid/base equilibria, see [lo]. For structural reasons, through-space interactions are negligible in such compounds. A steric effect was not detected by X-ray analysis. The interaction diagram was constructed according to the usual theoretical consider