✦ LIBER ✦
nucleophilic addition to C,C-double bonds. VII. Study of proximity effects in olefinic alcohols and amines by photoelectron spectroscopy
✍ Scribed by Gerardo M. Ramos Tombo; Hans Jakob Ammann; Klaus Müller; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 416 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
The influence of steric compression on electronic structure in polycyclic olefinic alcohols and amines is studied by PE. spectroscopy.
The unsubstituted alcohol 2 and amine 7 show PE.‐spectroscopic properties that can be reconciled by postulating a predominance of intramolecularly H‐bonded species in the gas phase.
For the alkylated derivatives 5 and 9, in which H‐bonding is precluded, distinct, but only moderate lone‐pair double‐bond interactions are observed.