𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Nucleophilic Acylation of o-Quinone Methides: An Umpolung Strategy for the Synthesis of α-Aryl Ketones and Benzofurans

✍ Scribed by Mattson, Anita E.; Scheidt, Karl A.


Book ID
111919377
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
67 KB
Volume
129
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Nucleophilic acylation of α-haloketones
✍ Santosh Singh; Pankaj Singh; Vijai K. Rai; Ritu Kapoor; Lal Dhar S. Yadav 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 441 KB

The first example of N-heterocyclic carbene (NHC)-promoted intermolecular acylation of a-haloketones with aldehydes and a,b-unsaturated aldehydes (enals) is reported. The protocol involves carbonyl umpolung reactivity of aldehydes and enals in which the carbonyl carbon attacks nucleophilically on el

Catalytic Additions of Acylsilanes to Im
✍ Anita E. Mattson; Karl A. Scheidt 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 25 KB

2005 ## Amines Q 0120 Catalytic Additions of Acylsilanes to Imines: An Acyl Anion Strategy for the Direct Synthesis of α-Amino Ketones. -The title methodology enables direct formation of N-phosphinylated amino ketones and completely avoids benzoin formation. The reaction tolerates structural div